Could user block after they switch profile

I have 5 profile types...

1. Register users and High School, they are auto login
2. Bachelor, Master and PHP Degree, I set them to admin approve after they sign up even though they sign up with Facebook or Twitter..

Now my user sign up Register and High School, they can switch to Bachelor, Master and PHP very well..

Could we make them to block after they switch to Bachelor, Master and PHP Degree because these profile need to upload their certificate to approve their levels are bachelor, master and PHD if they really so the admin can active for them. If they are not real so we switch their account to Register user or High Schoo...

Thank you..