Hello Damir Pečnik,
I am really sorry for the delay of this reply as it is a weekend for us here.
Unfortunately it is not possible to assign a moderator for a post automatically when the user create new discussion.
If you turn on "Moderate all new posts" while you set the category permission to specify user or user group "Who can moderate this category" (
http://screencast.com/t/cimnQJZTlA ), when the user post a new discussion, it will automatically send the email notification to the who assigned this category that moderator and superuser.Hope this help.